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The synthesis from myo-inositol of two bicyclic fused ring analogues of 1D-myo-inositol 1,4,5-trisphosphate in optically active form is described. The route demonstrates the application of the recently described butane-2,3- diacetal (BDA) protecting group to inositol chemistry, and features a novel construction of a dioxabicyclo[5.4.0]system using 3-chloro-2-chloromethyl-1- propene.

Original publication

DOI

10.1016/S0040-4039(99)00174-4

Type

Journal article

Journal

Tetrahedron Letters

Publication Date

12/03/1999

Volume

40

Pages

2213 - 2216